Structural isomerism in R3PSe(Ph)I compounds: the ionic structure of [(Me2N)3PSePh]I
Identifieur interne : 001817 ( Main/Exploration ); précédent : 001816; suivant : 001818Structural isomerism in R3PSe(Ph)I compounds: the ionic structure of [(Me2N)3PSePh]I
Auteurs : Stephen M. Godfrey [Royaume-Uni] ; Ruth T. A. Ollerenshaw [Royaume-Uni] ; Robin G. Pritchard [Royaume-Uni] ; Claire L. Richards [Royaume-Uni]Source :
- Journal of the Chemical Society, Dalton Transactions [ 1472-7773 ] ; 2001.
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Abstract
The reaction of two mole equivalents of (Me2N)3P with Ph2Se2I2 produces the ionic compound [(Me2N)3PSePh]I which contains a long Se–I contact, 3.825(1) Å, and a bent P–Se–I angle, 114.5(2)°.
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Ollerenshaw</name><affiliation wicri:level="3"><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea>Department of Chemistry, University of Manchester Institute of Science and Technology, M60 1QD, Manchester</wicri:regionArea><placeName><settlement type="city">Manchester</settlement><region type="country">Angleterre</region><region type="région" nuts="1">Grand Manchester</region></placeName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">Royaume-Uni</country></affiliation></author><author wicri:is="90%"><name sortKey="Pritchard, Robin G" sort="Pritchard, Robin G" uniqKey="Pritchard R" first="Robin G." last="Pritchard">Robin G. Pritchard</name><affiliation wicri:level="3"><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea>Department of Chemistry, University of Manchester Institute of Science and Technology, M60 1QD, Manchester</wicri:regionArea><placeName><settlement type="city">Manchester</settlement><region type="country">Angleterre</region><region type="région" nuts="1">Grand Manchester</region></placeName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">Royaume-Uni</country></affiliation></author><author wicri:is="90%"><name sortKey="Richards, Claire L" sort="Richards, Claire L" uniqKey="Richards C" first="Claire L." last="Richards">Claire L. Richards</name><affiliation wicri:level="3"><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea>Department of Chemistry, University of Manchester Institute of Science and Technology, M60 1QD, Manchester</wicri:regionArea><placeName><settlement type="city">Manchester</settlement><region type="country">Angleterre</region><region type="région" nuts="1">Grand Manchester</region></placeName></affiliation><affiliation wicri:level="1"><country wicri:rule="url">Royaume-Uni</country></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of the Chemical Society, Dalton Transactions</title><title level="j" type="abbrev">J. Chem. Soc., Dalton Trans.</title><idno type="ISSN">1472-7773</idno><idno type="eISSN">1364-5447</idno><imprint><publisher>The Royal Society of Chemistry.</publisher><date type="published" when="2001">2001</date><biblScope unit="volume">0</biblScope><biblScope unit="issue">5</biblScope><biblScope unit="page" from="508">508</biblScope><biblScope unit="page" to="509">509</biblScope></imprint><idno type="ISSN">1472-7773</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1472-7773</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="Teeft" xml:lang="en"><term>Adduct</term><term>Boyle</term><term>Chem</term><term>Dalton trans</term><term>Diethyl solution</term><term>Godfrey</term><term>Ionic structure</term><term>Large crop</term><term>Linear arrangement</term><term>Lone pair</term><term>Mole equivalents</term><term>Phosphine</term><term>Pritchard</term><term>Selenium</term><term>Solvent cdcl3</term><term>Special nitrogen</term><term>Structural nature</term><term>Trans</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract">The reaction of two mole equivalents of (Me2N)3P with Ph2Se2I2 produces the ionic compound [(Me2N)3PSePh]I which contains a long Se–I contact, 3.825(1) Å, and a bent P–Se–I angle, 114.5(2)°.</div></front></TEI><affiliations><list><country><li>Royaume-Uni</li></country><region><li>Angleterre</li><li>Grand Manchester</li></region><settlement><li>Manchester</li></settlement></list><tree><country name="Royaume-Uni"><region name="Angleterre"><name sortKey="Godfrey, Stephen M" sort="Godfrey, Stephen M" uniqKey="Godfrey S" first="Stephen M." last="Godfrey">Stephen M. Godfrey</name></region><name sortKey="Godfrey, Stephen M" sort="Godfrey, Stephen M" uniqKey="Godfrey S" first="Stephen M." last="Godfrey">Stephen M. Godfrey</name><name sortKey="Ollerenshaw, Ruth T A" sort="Ollerenshaw, Ruth T A" uniqKey="Ollerenshaw R" first="Ruth T. A." last="Ollerenshaw">Ruth T. A. Ollerenshaw</name><name sortKey="Ollerenshaw, Ruth T A" sort="Ollerenshaw, Ruth T A" uniqKey="Ollerenshaw R" first="Ruth T. A." last="Ollerenshaw">Ruth T. A. Ollerenshaw</name><name sortKey="Pritchard, Robin G" sort="Pritchard, Robin G" uniqKey="Pritchard R" first="Robin G." last="Pritchard">Robin G. Pritchard</name><name sortKey="Pritchard, Robin G" sort="Pritchard, Robin G" uniqKey="Pritchard R" first="Robin G." last="Pritchard">Robin G. Pritchard</name><name sortKey="Richards, Claire L" sort="Richards, Claire L" uniqKey="Richards C" first="Claire L." last="Richards">Claire L. Richards</name><name sortKey="Richards, Claire L" sort="Richards, Claire L" uniqKey="Richards C" first="Claire L." last="Richards">Claire L. Richards</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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